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Cambridge 0625 IGCSE  ·  Topic E2.8

E2.8 Specific Heat Capacity Equations & Calorimetry

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Thermal capacity measures how much thermal energy a body absorbs per unit temperature rise. Deriving and applying the specific heat capacity equation c=ΔE/(mΔθ)c = \Delta E / (m \Delta \theta) is essential for thermal engineering and calorimetry in Cambridge IGCSE Physics.

01 — Explanation

Core Principles of Specific Heat Capacity

Different materials require different quantities of thermal energy to raise the temperature of a unit mass by one degree.

Definition of Specific Heat Capacity

Specific heat capacity (cc) is defined as the thermal energy required per unit mass to increase the temperature of a substance by 1∘C1^\circ\text{C} (or 1 K1\text{ K}).

c=ΔEmΔθc = \frac{\Delta E}{m \Delta \theta}

Where:

  • ΔE\Delta E is thermal energy transferred in Joules (J)
  • mm is mass of the substance in kilograms (kg)
  • Δθ\Delta \theta is temperature change in ∘extC^\circ ext{C} or Kelvin (K)
  • cc is specific heat capacity in J / (kg ∘extC)\text{J / (kg }^\circ ext{C)}

Rearranging gives the thermal transfer equation:

ΔE=mcΔθ\Delta E = m c \Delta \theta

Water possesses an exceptionally high specific heat capacity (cwater≈4200 J/(kg ∘C)c_{\text{water}} \approx 4200\text{ J/(kg }^\circ\text{C)}), making it an effective coolant for car engines and power stations. Metals have low specific heat capacities (e.g. ccopper≈390 J/(kg ∘C)c_{\text{copper}} \approx 390\text{ J/(kg }^\circ\text{C)}), heating up rapidly when thermal energy is applied.

02 — Explanation

Electrical Measurement Protocol for c

To measure the specific heat capacity of a metal block in a laboratory:

  1. Measure mass mm of the metal block on an electronic balance.
  2. Insert an electric immersion heater and a digital thermometer into oil-filled holes in the block.
  3. Wrap the block in insulating lagging to minimize heat loss to surroundings.
  4. Record initial temperature θ1\theta_1.
  5. Connect heater to a d.c. supply with ammeter and voltmeter. Turn on for time tt seconds.
  6. Record current II, voltage VV, and final maximum temperature θ2\theta_2.
  7. Calculate electrical energy supplied: ΔE=IVt\Delta E = I V t.
  8. Calculate specific heat capacity:
c=IVtm(θ2−θ1)c = \frac{I V t}{m (\theta_2 - \theta_1)}

03 — Explanation

Key Terms and Definitions

TermSymbol / UnitDefinition
Specific Heat Capacity (cc)J/(kg ∘C)\text{J/(kg }^\circ\text{C)}Energy required per kg to raise temperature by 1∘extC1^\circ ext{C}.
Thermal Energy (ΔE\Delta E)Joule (J)Total internal energy change (ΔE=mcΔθ\Delta E = mc\Delta\theta).
Electrical EnergyIVtIVt (J)Heat energy supplied by electric heater in calorimetry.

Advanced Physical Analysis

Evaporation occurs at any temperature below boiling as energetic surface liquid molecules escape into gas, cooling the remaining liquid by removing average kinetic energy.

Extended Experimental Procedures and Quantitative Analysis

Experimental investigations require meticulous measurement and systematic error reduction. Digital timers, micrometers, and vernier calipers reduce uncertainty. Data analysis involves plotting linear graphs, calculating gradients to represent rate of change or physical constants, and comparing experimental values against theoretical expectations to quantify percentage error (∣Exp−Theo∣/Theo×100%|\text{Exp} - \text{Theo}| / \text{Theo} \times 100\%).

04 — Explanation

Conclusion

Specific heat capacity c=ΔE/(mΔθ)c = \Delta E / (m \Delta \theta) quantifies thermal energy requirements. High cc materials like water store large thermal energy with small temperature changes.